WAEC Chemistry Past Questions & Answers - Page 43

211.

Which of the following compounds is formed by the oxidation of ethanol?

A.

C\(_2\)H\(_4\)CO\(_2\)H

B.

C\(_2\)H\(_5\)CO\(_2\)H

C.

CH\(_3\)OH

D.

CH\(_3\)CO\(_2\)H

Correct answer is D

-Potassium dichromate solution is acidified with dilute sulphuric acid to oxidise ethanol into ethanoic acid.

212.

If the value of ΔH is positive for a reaction, it means that the reaction is?

A.

exothermic

B.

endothermic

C.

spontaneous

D.

slow

Correct answer is B

- Endothermic reactions are chemical reactions in which the reactants absorb heat energy from the surroundings to form products.

-  A system of reactants that absorbs heat from the surroundings in an endothermic reaction has a positive ΔH.

 examples of endothermic processes:

  • Melting ice cubes.
  • Melting solid salts.
  • Sublimation of dry ice into carbon dioxide gas.
  • Evaporating liquid water.

213.

When quicklime dissolves in water?

A.

heat is absorbed

B.

heat is evolved

C.

oxygen is liberated

D.

hydrogen is given off

Correct answer is B

- When quicklime is added to water, it forms slaked lime along with the evolution of heat. There will be a rise in the temperature of the bucket. Calcium oxide reacts with water to form calcium hydroxide, also called slaked lime.

- That is adding water to quicklime produces an exothermic reaction (gives out heat) and hydrated lime.

214.

Which of the following pairs of substances has the highest heat of neutralization?

A.

strong acid and strong base

B.

weak acid and weak base

C.

strong acid and weak base

D.

weak acid and strong base

Correct answer is A

In other terms, the stronger the acid the greater the amount of hydrogen ions present in the solution, and hence the more alkali that should be required to neutralise the solution, hence increasing the enthalpy

215.

Consider the following reaction equation: 2Al(OH)\(_3\) + 3H\(_2\)SO\(_4\) Al\(_2\)(SO4)\(_3\)(aq)+6H\(_2\)O. How many moles of tetraoxosulphate(vi)acid is needed to produce 0.5mol of aluminium tetraoxosulphate(vi)?

A.

0.5

B.

1.0

C.

1.5

D.

3.0

Correct answer is C

Where 3mols of H2So4 = 1 mol of (Al2SO4)3
y mols of H2SO4 = 0.5 mol of (Al2SO4)3
Then cross multiply to have:
y = \(\frac{3×0.5}{1}\)
y = 1.5 moles