JAMB Chemistry Past Questions & Answers - Page 260

1,296.

A solid begins to melt when?

A.

constituent particles acquires a greater kinetic energy

B.

energy of vibration of particles of the solid is less than the intermolecular forces

C.

constituent particles acquires energy above the average kinetic energy

D.

energy of vibration of particles of the solid equals the intermolecular forces

Correct answer is D

When a solid is heated, the particles are given more energy and start to vibrate faster. At a certain temperature, the particles vibrate so much that their ordered structure breaks down. At this point the solid melts into liquid.

1,298.

30cm3 of hydrogen was collected over water at 27°C and 780 mm Hg. If the vapour pressure of water at the temperature of the experiment was 10 mm Hg, calculate the volume of the gas at 760 mm Hg and 7°C?

A.

40.0 cm3

B.

35.7 cm3

C.

28.4 cm3

D.

25.2 cm3

Correct answer is C

Y1 = 30cm3 T1 = 27 + 273 = 300K and P1 = (780 - 10)mm Hg i.e the pressure minus the vapour pressure of water
P2 = 760mm Hg and T2 = 7 + 273 = 280K
From (P2V2) / (T2) = (P1V1) / (T1)
(770 x 30) / (300) = (760 x O2) / (280)
V2 = (770 x 30x 280) / (300 x 760)
V2 = 28.4 cm3

1,299.

C3H8(g) + 502(g) → 4H2O + 3CO2(g). Form the equation above the volume of oxygen at s.t.p. required to burn 50cm3 of propane is?

A.

250 cm3

B.

150 cm3

C.

100 cm 3

D.

50 cm3

Correct answer is A

C3H8 + 502 → 4H2O + 3CO2.
From the equation above 1 dm3 of C3H8 require 5dm3 of O2 at s.t.p.
∴ 50cm3 of C3H8 require x = (50) / (1000) x 5 x 1
x = (250) / (1000)
x = 250cm

1,300.

8.0 g of an element X react with an excess of copper (ll) tetraoxosulphate (lV) solution to deposit 21.3 g of copper. The correct equation for the reaction is?

(Cu = 64).

A.

X(s) + CuSO4(aq) → Cu(s) + XSO4(aq)

B.

X(s) + 2CuSO4(aq) → 2Cu(s) + X(SO4)2(aq)

C.

2X(s) + CuSO4(aq) → Cu(s) + X2SO4(aq)

D.

2X(s) + 3CuSO4(aq) → 3Cu(s) + X2(SO4)3(aq)

Correct answer is A

No explanation has been provided for this answer.