Methanoic acid mixes with water in all proportions and has about the same boiling point as water. Which of the following methods would you adopt to obtain pure water from a mixture of Sand, water and methanoic acid?

A.

Extractive distillation

B.

Filtration followed by distillation

C.

Neutralization with sodium hydroxide followed by distillation

D.

Neutralization with sodium hydroxide followed by filtration

Correct answer is A

Due to the presence of maximum Azeotrope,we use extractive distilination (with extractive distilation agents like sulfone) used for mixtures with low relative volatility,nearing unity.

Azeotrope is a mixture of liquids that has a constant boiling point because the vapour has thesame composition as the mixture.