Which of these solutions will give a white precipitate with a solution of barium chloride acidified with hydrochloric acid?

A.

Sodium trioxocarbonate (IV)

B.

Sodium tetraoxosulphate (IV)

C.

Sodium trioxosulphate (IV)

D.

Sodium sulphide

Correct answer is B

The characteristic test for any soluble tetraoxosulphate(VI) is the formation of white precipitate (barium sulphate) when a solution of barium chloride, acidified with dilute HCl, or when a solution of barium nitrate, acidified with dilute nitric acid is reacted with it.